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Pyrolysis gasolineorPygasis a naphtha-range product with a high aromatics content. It is a by-product of high temperature naphtha cracking during ethylene and propylene production. PyGas has high potential for use as a gasoline blending mixture and/or as a source of aromatics. Currently, PyGas is generally used as a gasoline blending mixture due to its high octane number. Pyrolysis gasoline can be blended with other hydrocarbons as a gasoline additive, or distilled (in BTX process) to separate it into its components, including benzene.
Petrol isa transparent, petroleum-derived liquid that is used primarily as a fuel in internal combustion engines. The characteristic of a particular gasoline blend to resist igniting too early (which causes knocking and reduces efficiency in reciprocating engines) is measured by its octane rating. Tetraethyllead and other lead compounds are no longer used in most areas to regulate and increase octane-rating, but many other additives are put into gasoline to improve its chemical stability, control corrosiveness and provide fuel system cleaning, and determine performance characteristics under intended use. Sometimes, gasoline also contains ethanol as an alternative fuel, for economic or environmental reasons.
Properties | Unit | Specification | Test Method |
Density @20 °C | g/cm3 | 0.725 Max | ASTM D 1298 |
Color | Saybolt | Light/ Red, Yellow | – |
Total Sulfur | ppm | 500 Max | ASTM D 4294 |
Lead Content | ppb | 10 Max | A.A |
IBP | °C | 35 Min | ASTM D 86 |
FBP | °C | 210 Max | ASTM D 86 |
Paraffin Naphthenes | %Wt | 40 Min | G.C |
Aromatics | %Wt | 25 Max | G.C |
Others | %Wt | 15 Max | G.C |
RON | 85 Min | Infrared |
Gasoline A-92
Properties | Unit | Specification | Test Method |
Density@ 20 °C | g/ml | 0.755 Max | ASTM D 1298 |
Color | Saybolt | Light Red/Yellow | – |
Total Sulfur | ppm | 100 Max | ASTM D 4294 |
Lead Content | ppb | 10 Max | A.A |
IBP | °C | 35 Min | ASTM D 86 |
FBP | °C | 210 Max | ASTM D 86 |
Paraffin Naphthenes | %Wt | 30 Min | G.C |
Aromatics | %Wt | 35 Max | G.C |
Benzene | %Wt | 1 Max | G.C |
Others | %Wt | 15 Max | G.C |
RON | 92 Min | Infrared | |
MON | 84 Min | Infrared |
Gasoline A-95
Properties | Unit | Result | Expected | Test Method |
Density @15°C | g/cm3 | 0.7391 | 710 min – 780 max | ASTM D 1298 |
RON | 95.2 | 95 min | ASTM D 2699 | |
MON | 85.2 | 85 min | ASTN D 2700 | |
RVP @ 37.8°C | kPa | 63.2 | 49 min – 83 max | ASTM D 323 |
Distillation, 10% vol. recovered | °C | 50.3 | 74 max | ASTM D 86 |
Distillation, 50% vol. recovered | °C | 82.2 | 127 max | ASTM D 86 |
Distillation, 90% vol. recovered | °C | 167.1 | 190 max | ASTM D 86 |
FBP | °C | 202.6 | 225 max | ASTM D 86 |
Olefins Content | %Vol | 9.5 | 26 max | ASTM D 1319 |
Aromatics Content | %Vol | 26.7 | 35 max | ASTM D 5580 |
Benzene Content | %Vol | 0.64 | 1 max | ASTM D 5580 |
Oxygenates (MTBE) | %Vol | 12.9 | 15 max | ASTM D 4815 |
Total Sulfur Content | ppm | 11 | 150 max | ASTM D 5453 |
Lead content | g/L | <0.0025 | Nil | ASTN D 3237 |
Color | Undyed | Report | Visual |
Dry Pyrolysis Gasoline (DPG)
Properties | Unit | Result | Expected | Test Method |
Density @15.6 °C | g/cm3 | 0.85 | 0.9 Max | ASTM D 4052 |
RVP | psi | 6.5 | Report | ASTM D 323 |
Total Sulfur | ppm | 180 | Report | ASTM D 5453 |
IBP | °C | 38 | Report | ASTM D 86 |
FBP | °C | 185 | Report | ASTM D 86 |
5% Vol Recovered | °C | 51 | Report | ASTM D 86 |
95% Vol Recovered | °C | 177 | Report | ASTM D 86 |
Paraffin | %Wt | 2.1 | Max 3 | G.C |
Olefins | %Wt | 24.5 | Max 30 | G.C |
Naphthenes | %Wt | 0.4 | Max 0.6 | G.C |
Aromatics | %Wt | 66.4 | 60 Min | G.C |
Others | %Wt | 6.6 | 20 Max | G.C |
Benzene Content | %Wt | 42.4 | 40 Min | G.C |
Hydrogenated Pyrolysis Gasoline (HPG)
Properties | Unit | Specification | Test Method |
Specific gravity @15°C | 0.78 – 0.84 | ASTM D 1298 | |
Color | Saybolt | + 5 Min. | ASTM D 156 |
RVP | psi | 5 – 12 | ASTM D 323 |
IBP | °C | 34 Min. | ASTM D 86 |
FBP | °C | 210 Max. | ASTM D 86 |
Aromatics | %Wt | 50 Min. | By GC |
Total Sulfur | ppm (wt) | 300 Max. | ASTM D 3120 |
Copper Corrosion | No. 1a | ASTM D 130 | |
Lead Content | ppb | 5 Max. | ATOMIC |
Naphthais a general term that has been used for over two thousand years to refer to flammable liquid hydrocarbon mixtures. Mixtures labelled naphtha have been produced from natural gas condensates, petroleum distillates, and the distillation of coal tar and peat. It is used diversely in different industries and regions to refer to gross products like crude oil or refined products such as kerosene. According to boiling points, Lightnaphthais the fraction boiling between 30C and 90C and consists of molecules with 56 carbon atoms.Heavy naphthaboils between 90C and 200C and consists of molecules with 612 carbons. Based on hydrocarbon structure, Light is a mixture consisting mainly of straight-chained and cyclic aliphatic hydrocarbons having from five to nine carbon atoms per molecule.Heavyis a mixture consisting mainly of straight-chained and cyclic aliphatic hydrocarbons having from seven to nine carbons per molecule
Properties | Unit | Specification | Test Method |
Density@ 20 °C | g/ml | 0.73 – 0.76 | ASTM D 1298 |
Lead Content | ppb | 10 Max | A.A |
IBP | °C | 60 Min | ASTM D 86 |
FBP | °C | 180 Max | ASTM D 86 |
Paraffinic & Naphthenic | %Wt | 70 Min | G.C |
Aromatic | %Wt | 30 Max | G.C |
Total Sulfur | ppm | 1700 Max | ASTM D 4294 |
Color | Clear – Light Yellow | Visual | |
RON | 75 Min | Infrared |
Heavy Naphtha
Properties | Unit | Specification | Test Method |
IBP | °C | 165 -179 | ASTM D-86 |
10% | °C | 177-186 | ASTM D-86 |
30% | °C | 182-194 | ASTM D-87 |
50% | °C | 190-205 | ASTM D-88 |
90% | °C | 250-280 | ASTM D-89 |
FBP | °C | 297-330 | ASTM D-90 |
Total Sulfur | ppm (wt) | 1400 Max. | ASTM D-3120 |
Color | ASTM | 2.0 Max. | ASTM D-1500 |
Flash point | °C | 58 Min. | ASTM D-93 |
Density @ 15 °C | g/ml | 0.7800 – 0.8400 | ASTM D-4052 |
Base oilsare used to manufacture products including lubricating greases, motor oil and metal processing fluids. Different products require different compositions and properties in the oil. One of the most important factors is the liquids viscosity at various temperatures.
Group Iconsists of conventional petroleum base oils. API defines group I as base stocks contain less than 90 percent saturates and/or greater than 0.03 percent sulfur and have a viscosity index greater than or equal to 80 and less than 120.
Group II arebase stocks contain greater than or equal to 90 percent saturates and less than or equal to 0.03 percent sulfur and have a viscosity index greater than or equal to 80 and less than 120.
Group III arebase stocks contain greater than or equal to 90 percent saturates and less than or equal to 0.03 percent sulfur and have a viscosity index greater than or equal to 120. This group may be described as Synthetic Technology oils or Hydro-Cracked Synthetic oil. However, some oil companies may call their products under this group as synthetic oil.
Group IV consists of synthetic oils made of Poly-alpha-olefins. PAO oils are much more stable in extreme temperatures, which make much more suitable for use in very cold weather as well as very hot weather.
Group V are any type of base oil other than mentioned in the previously defined groups. They include, among others, naphthenic oils and esters.
Properties | Unit | Min. | Typical | Max. | Test Method |
Kinematic Viscosity @40°C | cSt | – | 38 | – | ASTM D 445 |
Kinematic Viscosity @100°C | cSt | 4.6 | – | 5.6 | ASTM D 445 |
Viscosity Index | 100 | – | – | ASTM D 2270 | |
Flash Point (COC) | °C | 190 | – | – | ASTM D 92 |
Pour Point | °C | – | – | -6 | ASTM D 97 |
CCR | %Wt | – | 0.06 | – | ASTM D 189 |
Total Acidity | mgKOH/g | – | – | 0.05 | ASTM D 664 |
Demulsibility | – | Pass | – | ASTM D 1401 | |
Sulfur Content | %Wt | 0.15 | – | 0.6 | ASTM D 1552 |
Color | – | 0.5 | 1 | ASTM D 1500 | |
Density @15°C | kg/m³ | – | 875 | – | ASTM D 1298 |
Copper Corrosion, 3 hrs @100°C | – | – | 1A | ASTM D 130 | |
Foam | ml | – | Nil | – | ASTM D 892 |
Base Oil SN350
Properties | Unit | Min. | Typical | Max. | Test Method |
Kinematic Viscosity @40°C | cSt | – | 75 | – | ASTM D 445 |
Kinematic Viscosity @100°C | cSt | 8.3 | – | 9.3 | ASTM D 445 |
Viscosity Index | 95 | – | – | ASTM D 2270 | |
Flash Point (COC) | °C | 220 | – | – | ASTM D 92 |
Pour Point | °C | – | – | -6 | ASTM D 97 |
CCR | %Wt | – | 0.06 | – | ASTM D 189 |
Total Acidity | mgKOH/g | – | – | 0.05 | ASTM D 664 |
Demulsibility | – | Pass | – | ASTM D 1401 | |
Sulfur Content | %Wt | 0.15 | – | 0.6 | ASTM D 1552 |
Color | – | 2 | 1 | ASTM D 1500 | |
Density @15°C | kg/m³ | – | 880 | – | ASTM D 1298 |
Copper Corrosion, 3 hrs @100°C | – | – | 1A | ASTM D 130 | |
Foam | ml | – | Nil | – | ASTM D 892 |
Base Oil SN500
Properties | Unit | Min. | Typical | Max. | Test Method |
Kinematic Viscosity @40°C | cSt | – | 96 | – | ASTM D 445 |
Kinematic Viscosity @100°C | cSt | 10 | – | 11.5 | ASTM D 445 |
Viscosity Index | 95 | – | – | ASTM D 2270 | |
Flash Point (COC) | °C | 230 | – | – | ASTM D 92 |
Pour Point | °C | – | – | -6 | ASTM D 97 |
CCR | %Wt | – | 0.08 | 0.15 | ASTM D 189 |
Total Acidity | mgKOH/g | – | – | 0.05 | ASTM D 664 |
Demulsibility | – | Pass | – | ASTM D 1401 | |
Sulfur Content | %Wt | – | 0.7 | – | ASTM D 1552 |
Color | – | 2.5 | – | ASTM D 1500 | |
Density @15°C | kg/m³ | – | 885 | – | ASTM D 1298 |
Copper Corrosion, 3 hrs@100°C | – | Nil | – | ASTM D 130 | |
Foam | ml | – | Nil | – | ASTM D 892 |
Base Oil SN600
Properties | Unit | Specification |
Sp. Gr. @15.5°C | 0.8850-0.8950 | |
Color | 3.0 Max | |
Pour Point | °C | (-3) Max |
Flash Point | °C | 225 min |
Kinematic Viscosity @40°C | cSt | To be reported |
Kinematic Viscosity @100°C | cSt | 12.5 – 13.5 |
Viscosity Index | 90 min |
Ethylene oxide, properly calledoxirane, is a cyclic ether. It is one of the most important raw materials used in large-scale chemical production. Most ethylene oxide is used for synthesis of ethylene glycols, including diethylene glycol and triethylene glycol. Other important products include ethylene glycol ethers, ethanolamines and ethoxylates. Among glycols, ethylene glycol is used as antifreeze, in the production of polyester and polyethylene terephthalate (PET raw material for plastic bottles), liquid coolants and solvents.
Ethylene glycolis primarily used in antifreeze formulations (50%) and as a raw material in the manufacture of polyesters such as polyethylene terephthalate (PET) (40%). A small percent is also used in other applications such as and other products.
Coolant and heat transfer agent
The major use of ethylene glycol is as a medium for convective heat transfer in, for example, automobiles and liquid cooled computers. Ethylene glycol is also commonly used in chilled water air conditioning systems that place either the chiller or air handlers outside, or systems that must cool below the freezing temperature of water. In geothermal heating/cooling systems, ethylene glycol is the fluid that transports heat through the use of a geothermal heat pump. The ethylene glycol either gains energy from the source (lake, ocean, water well) or dissipates heat to the sink, depending if the system is being used for heating or cooling.
Antifreeze
Ethylene glycol disrupts hydrogen bonding when dissolved in water. Pure ethylene glycol freezes at about 12C, but when mixed with water, the mixture does not readily crystallize, and therefore the freezing point of the mixture is depressed. Specifically, a mixture of 60% ethylene glycol and 40% water freezes at 45C. It is used as a de-icing fluid for windshields and aircraft. The antifreeze capabilities of ethylene glycol have made it a component of vitrification mixtures for low-temperature preservation of biological tissues and organs.
Precursor to polymers
In the plastics industry, ethylene glycol is an important precursor to polyester fibers and resins. Polyethylene terephthalate, used to make plastic bottles for soft drinks, is prepared from ethylene glycol.
Properties | Unit | Specification | Test Method |
Purity | %Wt | 99.9 MIN | MA – 773 |
Color | Pt-Co | 5 MAX | DC – 139 |
Water Content | ppm | 100 MAX | VC – 261A |
Aldehydes as Acetaldehyde | ppm (wt) | 30 MAX | DC -163/A |
Acidity | ppm (wt) | 20 MAX | DC – 138 |
Residue | gr/100ML | 0.003 MAX | DC – 133 |
Acetylene | ppm | S – 414 – C | |
Suspended Matter | %Wt | DC – 139 |
Monoethylene Glycol (MEG)
Properties | Unit | Specification | Test Method |
Purity | %Wt | 99.8 MIN | ASTM E 202 |
Diethylene Glycol | %Wt | 0.08 MAX | ASTM E 202 |
Water Content | %Wt | 0.08 MAX | ASTM E 203 |
Acidity as Acetic Acid | ppm (wt) | 10 MAX | ASTM D 1613 |
Ash | gr/100ml | 0.005 MAX | DC – 254A |
Inorganic Chlorides (as Cl) | ppm (wt) | 0.05 MAX | EO – 635 |
Aldehydes as Acetaldehyde | ppm (wt) | 8 MAX | DC -163C |
Iron | ppm (wt) | 0.1 MAX | ASTM E 202 |
Color | Pt-Co | 5 MAX | ASTM D 1209 |
Sp. Gr. @20/20°C | 1.1151-1.1156 | ASTM D 891 | |
(5-95 vol%) | °C | 1 MAX | ASTM D 1078 |
Distillation@760mm Hg, IBP | °C | 196 MIN | ASTM D 1078 |
Distillation@760mm Hg, FBP | °C | 199 MAX | ASTM D 1078 |
UV Transmittance @220 nm | %T | 80 MIN | EO – 577A |
UV Transmittance @275 nm | %T | 95 MIN | EO – 577A |
UV Transmittance @350 nm | %T | 99 MIN | EO – 577A |
Diethylene Glycol (DEG)
Properties | Unit | Specification | Test Method |
Purity | %Wt | 99.8 MIN | ASTM E 202 |
Mono Ethylene Glycol | %Wt | 0.05 MAX | ASTM E 202 |
Tri Ethylene Glycol | %Wt | 0.05 MAX | ASTM E 202 |
Water Content | %Wt | 0.05 MAX | ASTM E 203 |
Acidity | %Wt | 0.005 MAX | ASTM D 1613 |
Ash | %Wt | 0.005 MAX | DC – 254/A |
SP.GR.@20/20°c | 1.1175-1.1195 | ASTM D 891 | |
Color | Pt-Co | 10 MAX | ASTM D 1209 |
Distillation@760mm Hg, IBP | °C | 242 MIN | ASTM D 1078 |
Distillation@760mm Hg, FBP | °C | 250 MAX | ASTM D 1078 |
Triethylene Glycol (TEG)
Properties | Unit | Specification | Test Method |
Purity | %Wt | 97 MIN | ASTM E 202 |
DEG | %Wt | 2 MAX | ASTM E 202 |
TEG (T.TEG) | %Wt | 1 MAX | ASTM E 202 |
Water | %Wt | 0.05 MAX | ASTM E 203 |
Acidity | %Wt | 0.01 MAX | ASTM D 1613 |
Ash | %Wt | 0.005 MAX | DC – 254/A |
Sp. Gr. @20/20°C | 1.124-1.126 | ASTM D 891 | |
Color | Pt-Co | 25 MAX | ASTM D 891 |
Distillation @760mm Hg (5-95 vol%) | °C | 280 MIN – 295 MAX | ASTM D 1078 |
Paraffin waxis a white or colorless soft solid derivable from petroleum, coal or oil shale, that consists of a mixture of hydrocarbon molecules containing between twenty and forty carbon atoms. It is solid at room temperature and begins to melt above approximately 37C;its boiling point is 370C. Common applications for paraffin wax include lubrication, electrical insulation, and candles. In industrial applications, it is often useful to modify the crystal properties of the paraffin wax, typically by adding branching to the existing carbon backbone chain. The modification is usually done with additives, such as EVA copolymers, microcrystalline wax, or forms of polyethylene.
Slack waxeshave an oil content of from 5 to 30%, depending on the product. They are a welcome by-product of the production of lubricating oils. They can be productively employed in many industrial processes as they are; or they can be mixed, blended, or further refined. The melting points of slack wax varies from 41F to 66F. Some examples of applications for slack waxes: in wax emulsions, as binders and water-proofing in artificial woods; in matches; in jar candles; in rust-protection products; in industrial lubricants; in arena-footing; in soil or turf protection; and in fireplace products.
Properties | Unit | Light Grade | Light Heavy Grade | Heavy Grade |
Oil Content | %Wt. | 2 max | 3 max | 5 max |
Congealing Point | °C | 56-58 | 59-64 | 63-71 |
Viscosity @ 100°C | cSt | 3.87-4.36 | 4.6-6.5 | 6.5-8.1 |
Refractive Index | RI | 1.43 5 0 | 1.43 8 0 | 1.443 0 |
Slack Wax
Properties | Unit | Specification | Test Method |
Kinematic Viscosity @100°C | cSt | 7-9 | 3 max |
Congealing Point | °C | 65-68 | 59-64 |
Density @15°C | kg/m³ | 830-850 | 4.6-6.5 |
Oil Content | RI | 30 max | 1.43 8 0 |
Refractive Index @70°C | 1.4520 | 1.43 8 0 | |
Color | Brownish | 1.43 8 0 |
High-density polyethylene(HDPE) is a polyethylene thermoplastic made from petroleum. It is sometimes called alkathene or polythene when used for pipes. With a high strength-to-density ratio, HDPE is used in the production of plastic bottles, corrosion-resistant piping, geomembranes, and plastic lumber. HDPE is commonly recycled, and has the number 2 as its resin identification code.
Linear low-density polyethylene(LLDPE) is a substantially linear polymer, with significant numbers of short branches, commonly made by copolymerization of ethylene with longer-chain olefins. Linear low-density polyethylene differs structurally from conventional low-density polyethylene (LDPE) because of the absence of long chain branching. The linearity of LLDPE results from the different manufacturing processes of LLDPE and LDPE. In general, LLDPE is produced at lower temperatures and pressures by copolymerization of ethylene and such higher alpha-olefins as butene, hexene, or octene. The copolymerization process produces an LLDPE polymer that has a narrower molecular weight distribution than conventional LDPE and in combination with the linear structure, significantly different rheological properties.
Polypropylene(PP), also known aspolypropene, is a thermoplastic polymer used in a wide variety of applications including packaging and labeling, textiles (e.g., ropes, thermal underwear and carpets), stationery, plastic parts and reusable containers of various types, laboratory equipment, loudspeakers, automotive components, and polymer banknotes. An addition polymer made from the monomer propylene, it is rugged and unusually resistant to many chemical solvents, bases and acids.
Grade Name | MFR(gr/10min) (5kg,190OC) | Density | Application |
AM 5010 T2 N (EX3) | 0.45 | 0.945 | PE-80 Pressure pipe, e.g. drinking water and gas pipes, waste pipes and sewer pipes, their fittings and also sheets (natural grade). |
AM 5010 T2 B (EX3B) | 0.45 | 0.954 | PE-80 Pressure pipes, e.g. drinking water and gas pipes, waste pipes and sewer pipes, their fittings and also sheets (black grade) |
AM 5010 T3 N | 0.43 | 0.944 | High quality PE-80 pressure pipe for gas and water transportation (natural grade). |
AM 5010 T3 B | 0.43 | 0.954 | High quality PE-80 pressure pipe for gas and water transportation (black grade). |
AM CRP 100 N (PE – 100 W) | 0.22 | 0.948 | Top quality PE-100 pressure pipes for gas and water transportation at higher pressures or with thinner walls as PE-80(natural grade). |
AM CRP 100 B PE – 100 B | 0.22 | 0.957 | Leading PE-100 for pressure pipes for all purposes for gas, water and sewage transportation (black grade). |
AM CRP 100 Blue (PE – 100 Blue) |
0.22 | 0.948 | Leading PE-100, specially for drinking water (blue marker) |
Extrusion – Stretched Film and tape (Basell license)
Grade Name | MFR(gr/10min) (5kg,190OC) | Density | Application |
AF 7740 F (EX 1) | 1.6 | 0.944 | Stretched films and tapes for production of high quality knitted and woven. |
AF 7740 F2 (EX1 S) | 1.8 | 0.944 | Tapes to be used for agricultural packaging and as protective cover. |
Ureais the worlds most commonly used nitrogen fertilizer and indeed more urea is manufactured by mass than any other organic chemical. Containing 46% N, it is the most concentrated nitrogen fertilizer, and is readily available as free-flowing prills (granules). While over 90% of urea produced is used as a fertilizer, it has other uses, which include the manufacture of the melamine, used in melamine-methanal resins. Urea itself also forms important resins. An increasingly important use of urea is in reducing air pollution from diesel engines in cars, buses and lorries.
Properties | Unit | Specification | Test Method |
Nitrogen | %Wt | 2 max | AOAC (1995) Method 955.04 (2.4.03) |
Biuret | %Wt | Report | AOAC (1995) Method 960.04 (2.4.03) |
Moisture | %Wt | Report | AOAC (1995) Method 972.01 (2.2.03) |
Formaldehyde | %Wt | 50 | UKF SBB 0071-02-E,ED,2 (1982) |
Particle Size | 2.0-4.0 min by %Wt | 55 | IV-A TFI-1982 |