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Industrial Chemicals #4112435

Ethylene Oxide

Ethylene Oxide & Ethylene Glycol

Ethylene oxide, properly calledoxirane, is a cyclic ether. It is one of the most important raw materials used in large-scale chemical production. Most ethylene oxide is used for synthesis of ethylene glycols, including diethylene glycol and triethylene glycol. Other important products include ethylene glycol ethers, ethanolamines and ethoxylates. Among glycols, ethylene glycol is used as antifreeze, in the production of polyester and polyethylene terephthalate (PET raw material for plastic bottles), liquid coolants and solvents.

Ethylene glycolis primarily used in antifreeze formulations (50%) and as a raw material in the manufacture of polyesters such as polyethylene terephthalate (PET) (40%). A small percent is also used in other applications such as and other products.

Coolant and heat transfer agent

The major use of ethylene glycol is as a medium for convective heat transfer in, for example, automobiles and liquid cooled computers. Ethylene glycol is also commonly used in chilled water air conditioning systems that place either the chiller or air handlers outside, or systems that must cool below the freezing temperature of water. In geothermal heating/cooling systems, ethylene glycol is the fluid that transports heat through the use of a geothermal heat pump. The ethylene glycol either gains energy from the source (lake, ocean, water well) or dissipates heat to the sink, depending if the system is being used for heating or cooling.

Antifreeze

Ethylene glycol disrupts hydrogen bonding when dissolved in water. Pure ethylene glycol freezes at about 12C, but when mixed with water, the mixture does not readily crystallize, and therefore the freezing point of the mixture is depressed. Specifically, a mixture of 60% ethylene glycol and 40% water freezes at 45C. It is used as a de-icing fluid for windshields and aircraft. The antifreeze capabilities of ethylene glycol have made it a component of vitrification mixtures for low-temperature preservation of biological tissues and organs.

Precursor to polymers

In the plastics industry, ethylene glycol is an important precursor to polyester fibers and resins. Polyethylene terephthalate, used to make plastic bottles for soft drinks, is prepared from ethylene glycol.

Properties Unit Specification Test Method
Purity %Wt 99.9 MIN MA – 773
Color Pt-Co 5 MAX DC – 139
Water Content ppm 100 MAX VC – 261A
Aldehydes as Acetaldehyde ppm (wt) 30 MAX DC -163/A
Acidity ppm (wt) 20 MAX DC – 138
Residue gr/100ML 0.003 MAX DC – 133
Acetylene ppm   S – 414 – C
Suspended Matter %Wt   DC – 139

Monoethylene Glycol (MEG)

Properties Unit Specification Test Method
Purity %Wt 99.8 MIN ASTM E 202
Diethylene Glycol %Wt 0.08 MAX ASTM E 202
Water Content %Wt 0.08 MAX ASTM E 203
Acidity as Acetic Acid ppm (wt) 10 MAX ASTM D 1613
Ash gr/100ml 0.005 MAX DC – 254A
Inorganic Chlorides (as Cl) ppm (wt) 0.05 MAX EO – 635
Aldehydes as Acetaldehyde ppm (wt) 8 MAX DC -163C
Iron ppm (wt) 0.1 MAX ASTM E 202
Color Pt-Co 5 MAX ASTM D 1209
Sp. Gr. @20/20°C   1.1151-1.1156 ASTM D 891
(5-95 vol%) °C 1 MAX ASTM D 1078
Distillation@760mm Hg, IBP °C 196 MIN ASTM D 1078
Distillation@760mm Hg, FBP °C 199 MAX ASTM D 1078
UV Transmittance @220 nm %T 80 MIN EO – 577A
UV Transmittance @275 nm %T 95 MIN EO – 577A
UV Transmittance @350 nm %T 99 MIN EO – 577A

Diethylene Glycol (DEG)

Properties Unit Specification Test Method
Purity %Wt 99.8 MIN ASTM E 202
Mono Ethylene Glycol %Wt 0.05 MAX ASTM E 202
Tri Ethylene Glycol %Wt 0.05 MAX ASTM E 202
Water Content %Wt 0.05 MAX ASTM E 203
Acidity %Wt 0.005 MAX ASTM D 1613
Ash %Wt 0.005 MAX DC – 254/A
SP.GR.@20/20°c   1.1175-1.1195 ASTM D 891
Color Pt-Co 10 MAX ASTM D 1209
Distillation@760mm Hg, IBP °C 242 MIN ASTM D 1078
Distillation@760mm Hg, FBP °C 250 MAX ASTM D 1078

Triethylene Glycol (TEG)

Properties Unit Specification Test Method
Purity %Wt 97 MIN ASTM E 202
DEG %Wt 2 MAX ASTM E 202
TEG (T.TEG) %Wt 1 MAX ASTM E 202
Water %Wt 0.05 MAX ASTM E 203
Acidity %Wt 0.01 MAX ASTM D 1613
Ash %Wt 0.005 MAX DC – 254/A
Sp. Gr. @20/20°C   1.124-1.126 ASTM D 891
Color Pt-Co 25 MAX ASTM D 891
Distillation @760mm Hg (5-95 vol%) °C 280 MIN – 295 MAX ASTM D 1078
 

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Waxes

Waxes

Paraffin waxis a white or colorless soft solid derivable from petroleum, coal or oil shale, that consists of a mixture of hydrocarbon molecules containing between twenty and forty carbon atoms. It is solid at room temperature and begins to melt above approximately 37C;its boiling point is 370C. Common applications for paraffin wax include lubrication, electrical insulation, and candles. In industrial applications, it is often useful to modify the crystal properties of the paraffin wax, typically by adding branching to the existing carbon backbone chain. The modification is usually done with additives, such as EVA copolymers, microcrystalline wax, or forms of polyethylene.

Slack waxeshave an oil content of from 5 to 30%, depending on the product. They are a welcome by-product of the production of lubricating oils. They can be productively employed in many industrial processes as they are; or they can be mixed, blended, or further refined. The melting points of slack wax varies from 41F to 66F. Some examples of applications for slack waxes: in wax emulsions, as binders and water-proofing in artificial woods; in matches; in jar candles; in rust-protection products; in industrial lubricants; in arena-footing; in soil or turf protection; and in fireplace products.

Properties Unit Light Grade Light Heavy Grade Heavy Grade
Oil Content %Wt. 2 max 3 max 5 max
Congealing Point °C 56-58 59-64 63-71
Viscosity @ 100°C cSt 3.87-4.36 4.6-6.5 6.5-8.1
Refractive Index RI 1.43 5 0 1.43 8 0 1.443 0

Slack Wax

Properties Unit Specification Test Method
Kinematic Viscosity @100°C cSt 7-9 3 max
Congealing Point °C 65-68 59-64
Density @15°C kg/m³ 830-850 4.6-6.5
Oil Content RI 30 max 1.43 8 0
Refractive Index @70°C   1.4520 1.43 8 0
Color   Brownish 1.43 8 0
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